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Note: To achieve the shortest possible runtime select the bigger entity in the "fixed chain" field and the smalller entity in the "scanning chain" field, unless you are specifically interested in the accessible interaction space of the smaller entity,

Add a custom tag to identify your run.
Perform an occupancy analysis, ultimately providing a volume where each grid point represents the normalized probability of that spot being occupied by the scanning chain

Rotational sampling interval in degree
Voxel spacing of sampling grid in angstrom.
Interaction radius of each atom in angstrom.
Maximum allowed volume of clashes in cubic angstrom
Minimum required volume of interaction in cubic angstrom

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You can find example input files here: EXAMPLE